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1. Do any of the dagger mastery's efects(critical chance double strike chance) apply to other weapons.
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Doublestriking only applies to daggers.
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2. Does the aditional critical chance from critical strikes apply to other weapons like scythes.
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Yes. Critical Strikes increases your chance to land a critical hit with any weapon (including spellcasting weapons).
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3. Can I use lead, offhand, dual attacks with scythes?
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No. Lead, offhand and dual attacks are all dagger attacks and may only be used while equipped with daggers.
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4. Are there any green scythes?
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Yes, there are green scythes. Google up the GW Wiki and hunt for green scythes on there - it will tell you what stats each green scythe has and which bosses they drop from.
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5. Is a A/D viable? And will it be able to spike like a pure assassin or at least close?
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Yes, an A/D is viable (any combination is viable with a little work). Although to really keep the spiking aspect, it would probably be better to stick with daggers as the weapon choice for the attack chains. Personally, if I was running an A/D I would go for Critical Strikes, Dagger Mastery and Earth Prayers (I speak from a PvE point of view here)