+30hp raw is the least valuable because it is functionally equivalent to DoA greens.
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Originally Posted by Bright Star Shine
Imo, +10/45 is better, especially in trench (4 lord), and also a lot more rare and hard to get, since health mods on gold shields can be imperfect, while the -2ench mod can never be (on a gold shield at least). Many debate that the -2ench is more effective, but honestly, once Shroud activates, the difference it makes is non-existent. I used to be a vigorous -2ench debater though, but I changed my opinion eventually, seeing that it really doesn't do shit..
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There are pulls where +45 enchanted is definitely better to have, but the flip side is that there are some pulls where -2 is better. Some of it even comes down to how you personally do some of the pulls, and it also depends on the compositions of the mobs. You'd gain a bigger benefit by swapping off of the superior shadow arts rune than you would with one shield or the other, regardless of the pull. Realistically it doesn't matter. If those miniscule differences will make or break your run on more than one in several hundred runs, you should be more concerned about the quality of your trenching.
Outside of veil the -2 is definitely a superior shield because you are aiming for continuous protection as opposed to relative burst damage.
As to value, that's more dependent on the skin. A +10 demon outcast/echovald shield is going to sell for quite a great deal of money regardless of it being -2/+45 enchanted.