Originally Posted by Anet
The PvP Access Kit also includes 60 free unlocks (20 elite skills, 20 normal skills and 20 items) to help you power up your game instantly. Mix and match with Skill and Item Unlock Packs to further enhance your PvP characters.
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As for unlocking the skills for a Chapter: if you buy that chapter's PVP unlcoks, they will immediately be available for use, no need for Balthazar faction.
(I can't help but add, the hype on this being good for PvE players is ridiculous. The better our Heros have it in PvE, the more I wish I had the same options for my Main...)